کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1256419 | 971473 | 2008 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Preparation of 2,6-diisopropylnaphthalene with recycled process of isomers
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی (عمومی)
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چکیده انگلیسی
2,6-Diisopropylnaphthalene (2,6-DIPN), as the precursor of important monomer 2,6-naphthalene dicarboxylic acid, was prepared by hydroisopropylation of refined naphthalene with propene over shape-selective catalyst. Naphthalene conversion of 92% and 2,6-DIPN selectivity of 64% were obtained. Static melt crystallization was applied to separate and purify 2,6-DIPN from its isomers, resulted in a product purity of â¥99%. The other isomers were converted into monoisopropylnaphthalene, which also reacted with propene to form 2,6-DIPN. A recycled process including hydroisopropylation, separation and transalkylation was established, the yield of 2,6-DIPN based on naphthalene could be doubled by one cycle operation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Chemical Letters - Volume 19, Issue 4, April 2008, Pages 390-394
Journal: Chinese Chemical Letters - Volume 19, Issue 4, April 2008, Pages 390-394
نویسندگان
Zheng Hua Tian, Gui Li Zhao, Hong Min Jia, Ben Li, Wei Qi Hu,