کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1256774 971529 2015 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Monofunctionalized pillar[5]arene-based stable [1]pseudorotaxane
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Monofunctionalized pillar[5]arene-based stable [1]pseudorotaxane
چکیده انگلیسی

We reported a new monofunctionalized pillar[5]arene bearing imidazolium moiety that formed stable [1]pseudorotaxane even at high concentration (100 mmol/L) in chloroform. The self-assembly was detailed investigated by multiple methods, including varying concentration 1H NMR, 2D COSY NMR, 2D NOESY NMR, viscosity measurements, 2D DOSY NMR, and HR-ESI-MS analysis. [1]Rotaxane was obtained efficiently through photo thiol-ene reaction which further confirmed the formation of [1]pseudorotaxane.

A new monofunctionalized pillar[5]arene bearing imidazolium moiety that formed stable [1]pseudorotaxane even at high concentration (100 mmol/L) was reported. [1]Rotaxane was obtained efficiently through thiol-ene reaction from [1]pseudorotaxane which further confirmed the formation of [1]pseudorotaxane.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Chemical Letters - Volume 26, Issue 7, July 2015, Pages 843–846
نویسندگان
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