کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1256774 | 971529 | 2015 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Monofunctionalized pillar[5]arene-based stable [1]pseudorotaxane Monofunctionalized pillar[5]arene-based stable [1]pseudorotaxane](/preview/png/1256774.png)
We reported a new monofunctionalized pillar[5]arene bearing imidazolium moiety that formed stable [1]pseudorotaxane even at high concentration (100 mmol/L) in chloroform. The self-assembly was detailed investigated by multiple methods, including varying concentration 1H NMR, 2D COSY NMR, 2D NOESY NMR, viscosity measurements, 2D DOSY NMR, and HR-ESI-MS analysis. [1]Rotaxane was obtained efficiently through photo thiol-ene reaction which further confirmed the formation of [1]pseudorotaxane.
A new monofunctionalized pillar[5]arene bearing imidazolium moiety that formed stable [1]pseudorotaxane even at high concentration (100 mmol/L) was reported. [1]Rotaxane was obtained efficiently through thiol-ene reaction from [1]pseudorotaxane which further confirmed the formation of [1]pseudorotaxane.Figure optionsDownload as PowerPoint slide
Journal: Chinese Chemical Letters - Volume 26, Issue 7, July 2015, Pages 843–846