کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1256917 | 971536 | 2016 | 4 صفحه PDF | دانلود رایگان |
An efficient copper-catalyzed decarboxylative hydroboration of phenylpropiolic acids with bis(pinacolato)diboron was developed, affording β-vinylboronates as the only products in high yields. Extra hydrogen sources such as methanol are not needed in this catalytic system. This reaction could be performed successfully under ligand- and base-free conditions. It demonstrated that phenylpropiolic acids can be employed as alkyne synthons in the hydroboration reaction and exhibited good reactivity and higher selectivity than terminal alkynes.
Copper-catalyzed decarboxylative hydroboration of phenylpropiolic acids with bis(pinacolato)diboron proceeds under ligand-free or both ligand- and base-free conditions, affording β-vinylboronates in high yields.Figure optionsDownload as PowerPoint slide
Journal: Chinese Chemical Letters - Volume 27, Issue 4, April 2016, Pages 571–574