کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1257492 | 971566 | 2012 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
An environmentally benign benzylic oxidation catalyzed by hypervalent iodine intermediate in water
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: An environmentally benign benzylic oxidation catalyzed by hypervalent iodine intermediate in water An environmentally benign benzylic oxidation catalyzed by hypervalent iodine intermediate in water](/preview/png/1257492.png)
چکیده انگلیسی
An effective and environmentally benign benzylic oxidation for transition of alkylarenes into the corresponding carbonyl compounds was reported. Alkylarenes were mixed and stirred with potassium bromide, m-chloroperbenzoic acid and a catalytic amount of iodobenzene in water at 60 °C for several hours, a series of the corresponding carbonyl compounds was obtained in moderate to good yields. In the reaction, iodobenzene was first oxidized by m-chloroperbenzoic acid into the hypervalent iodine intermediate which then reacted with potassium bromide to form the key radical initiator for the benzylic oxidation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Chemical Letters - Volume 23, Issue 8, August 2012, Pages 891–894
Journal: Chinese Chemical Letters - Volume 23, Issue 8, August 2012, Pages 891–894
نویسندگان
Yuan Xu, Jian Tao Hu, Jie Yan,