کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1258121 | 971600 | 2010 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Kinetic comparison between ferric ion and decamethyferrocene at the liquid/liquid interface as studied by scanning electrochemical microscopy
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Kinetic comparison between ferric ion and decamethyferrocene at the liquid/liquid interface as studied by scanning electrochemical microscopy Kinetic comparison between ferric ion and decamethyferrocene at the liquid/liquid interface as studied by scanning electrochemical microscopy](/preview/png/1258121.png)
چکیده انگلیسی
Comparison in electron transfer (ET) processes from decamethyferrocene (DMFe) in nitrobenzene (NB) to ferric ion in aqueous phase was investigated for the first time by the scanning electrochemical microscopy (SECM). As compared with the system of Fe(CN)63−–DMFe, the ET rate obtained from Fe3+–DMFe was lower in spite of larger driving force, which may arise from the effect of reorganization energy. Otherwise, the effect of common ion on rate constants was also probed and results suggested additional complexity of the ET mechanism between Fe(CN)63− and DMFe.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Chemical Letters - Volume 21, Issue 1, January 2010, Pages 89–92
Journal: Chinese Chemical Letters - Volume 21, Issue 1, January 2010, Pages 89–92
نویسندگان
Xiao Quan Lu, Jun Ying Ma, Xiu Hui Liu, Cun Wu Dong, Wen Ting Wang,