کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1258127 971600 2010 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The role of nickel(II) on the homochirality of amino acids in living systems
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
The role of nickel(II) on the homochirality of amino acids in living systems
چکیده انگلیسی
The origin of homochirality in living organisms is controversial, stands out of being particularly important and a question which is still not satisfactorily answered. A mental picture of sequence of events that is thought to have preceded the existence of chirality in molecules is described. A chemical model to mimic the original abiotic conditions in an attempt to explain the preference of homochirality in living systems was tried. The effect which might have influenced this preference is presented. The surprising and unexpected results are indeed interesting, significant, repeatable and indicate that complexing alanine with nickel(II) ion alters the racemization rates of d and l isomers of the amino acid. However, why this difference happens is unclear and is difficult to explain.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Chemical Letters - Volume 21, Issue 1, January 2010, Pages 113-116
نویسندگان
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