کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1258470 971619 2008 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Ultrafast cyclic voltammetry with asymmetrical potential scan
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Ultrafast cyclic voltammetry with asymmetrical potential scan
چکیده انگلیسی

Based on the perfect ohmic drop compensation by online electronic positive feedback, ultrafast cyclic voltammetry with asymmetrical potential scan is achieved for the first time, with the reduction of anthracene acting as the test system. Compared with the traditional cyclic voltammetry utilizing symmetrical triangular waveform as the excitation one, the new method allows a simpler approach to mechanistic analysis of ultrafast chemical reactions coupled with a charge transfer. And perhaps more important, it also provides a way to eliminate the interference of the adsorbed product in dynamic monitoring.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Chemical Letters - Volume 19, Issue 1, January 2008, Pages 85–88
نویسندگان
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