کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1258477 971619 2008 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Self-diffusion coefficients of organic solvents in linear and branched high density polyethylene particles measured by PFG NMR
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Self-diffusion coefficients of organic solvents in linear and branched high density polyethylene particles measured by PFG NMR
چکیده انگلیسی

Pulsed field gradient nuclear magnetic resonance (PFG NMR) has been performed to study the diffusion of organic solvents into semicrystalline polyethylene particles. Self-diffusion coefficients in different domains of the sample can be extracted through a bi-exponential fit to the echo intensity attenuation, which allows the precise determination of the tortuosity of the polyethylene particles. Further exploration comes from the measurements with branched polyethylene particles and it was found that the diffusion in polymer phase contributed significantly to the slow component of the exponential decay curve.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Chemical Letters - Volume 19, Issue 1, January 2008, Pages 110–114
نویسندگان
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