کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1263976 972093 2013 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Dry growth of n-octylphosphonic acid monolayer for low-voltage organic thin-film transistors
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Dry growth of n-octylphosphonic acid monolayer for low-voltage organic thin-film transistors
چکیده انگلیسی

Dry method for monolayer deposition of n-octylphosphonic acid (C8PA) on the surface of aluminium oxide (AlOx) is presented. Vacuum thermal evaporation is employed to deposit initial thickness corresponding to several C8PA monolayers, followed by a thermal desorption of the physisorbed C8PA molecules. AlOx functionalized with such C8PA monolayer exhibits leakage current density of ∼10−7 A/cm2 at 3 V, electric breakdown field of ∼6 MV/cm, and a root-mean-square surface roughness of 0.36 nm. The performance of low-voltage pentacene thin-film transistors that implement this dry AlOx/C8PA gate dielectric depends on C8PA desorption time. When the desorption time rises from 25 to 210 min, the field-effect mobility increases from ∼0.02 to ∼0.04 cm2/V s, threshold voltage rises from ∼−1.2 to ∼−1.4 V, sub-threshold slope decreases from ∼120 to ∼80 mV/decade, off-current decreases from ∼5 × 10−12 to ∼1 × 10−12 A, on/off current ratio rises from ∼3.8 × 104 to ∼2.5 × 105, and the transistor hysteresis decreases from 61 to 26 mV. These results collectively support a two stage model of the desorption process where the removal of the physisorbed C8PA molecules is followed by the annealing of the defect sites in the remaining C8PA monolayer.

Figure optionsDownload as PowerPoint slideHighlights
► Monolayer of n-octylphosphonic acid (C8PA) was formed by vacuum evaporation.
► C8PA surface exhibits RMS surface roughness of 0.36 nm and water contact angle of 107.4°.
► Aluminium oxide functionalized with C8PA monolayer forms a gate dielectric in low-voltage organic thin-film transistors.
► Completely dry process for bottom-gate, top-contact pentacene thin-film transistors is presented.
► Transistor performance is comparable to transistors implementing solution processed short-chain alkyl-PA monolayers.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Organic Electronics - Volume 14, Issue 1, January 2013, Pages 354–361
نویسندگان
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