کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1265543 | 972231 | 2008 | 12 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Green phosphorescent iridium dendrimers containing dendronized benzoimidazole-based ligands for OLEDs Green phosphorescent iridium dendrimers containing dendronized benzoimidazole-based ligands for OLEDs](/preview/png/1265543.png)
A series of novel non-conjugated functionalized benzoimidazole-based dendrimers containing peripheral benzyl ether type dendrons have been synthesized and characterized. These compounds undergo cyclometalation with iridium trichloride to form iridium(III) complexes. The emission wavelengths of these dendrimers are in the range from 510 to 530 nm, and the photoluminescence quantum yields (PLQYs) in the range from 0.45 to 0.80. Dendrimers (Gn)2Ir(acac) and (Gn)3Ir exhibit a reversible one-electron oxidation wave at ∼0.55 V and ∼0.37 V (vs. Ag/AgNO3), respectively. With a device configuration of indium tin oxide/poly(3,4-ethylenedioxythiophene):poly(styrene sulfonic acid)/4,4′-bis(N-carbarzolyl)biphenyl:(G2)3Ir 20 wt% dopant/1,3,5-tris(2-N-phenyl-benzoimidazolyl)benzene/LiF/Al has a maximum external quantum efficiency (EQE) of 17.6% and a maximum current efficiency of 61.5 cd/A.
Journal: Organic Electronics - Volume 9, Issue 5, October 2008, Pages 557–568