کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1267533 972358 2012 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Oligothiophene dendron-decorated squaraine dyes: Synthesis, thin film formation, and performance in organic solar cells
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Oligothiophene dendron-decorated squaraine dyes: Synthesis, thin film formation, and performance in organic solar cells
چکیده انگلیسی

Squaraine (SQ) dye-based organic semiconductor hybrids 6T-SQ and 18T-SQ functionalized with oligothiophene dendrons were synthesized via Suzuki–Miyaura coupling. The electronic coupling between the oligothiophene dendrons and the squaraine core was rather weak, as suggested from UV–vis spectra, cyclic voltammetry measurements and molecular modeling. Thin films of pure SQ were characterized by a pronounced solvent- and heat-induced crystallization tendency. The dendrons substantially hindered the squaraine core crystallization, and 18T-SQ films remained amorphous after annealing or storage for several weeks. PCBM disrupted dye crystallization in blends, and smooth and stable films could be coated. Heat treatment of blended films induced dewetting for SQ:PCBM and 6T-SQ:PCBM, but 18T-SQ:PCBM remained again stable. These morphological film features could consistently explain the performance of dye-fullerene solar cells. The best performance (η ∼ 1.5%) was obtained for simple bilayer 6T-SQ:C60 or 18T-SQ:C60 cells without annealing. Our results demonstrate that the attachment of decorating moieties to a central light-absorbing core unit in molecular push–pull systems can be used to adjust the optoelectronic and morphological film properties of small molecular semiconductors with a strong tendency towards crystallization.

Figure optionsDownload as PowerPoint slideHighlights
► Oligothiophene dendron–squaraine hybrids were used as donors in organic solar cells.
► The electronic coupling between the dendrons and the squaraine core was rather weak.
► The dendrons substantially hindered the pronounced squaraine dye crystallization.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Organic Electronics - Volume 13, Issue 7, July 2012, Pages 1204–1212
نویسندگان
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