کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1268268 | 972399 | 2009 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Second order nonlinear optical networks with excellent poling stability from a new trifunctional thiophene based chromophore Second order nonlinear optical networks with excellent poling stability from a new trifunctional thiophene based chromophore](/preview/png/1268268.png)
Two new trifunctional thiophene based dyes suited for crosslinking were synthesised from the same structural core, i.e. 4-[[5-[(4-nitrophenyl)azo]-2-thienyl]azo]benzenamine. Crystal structure and second order nonlinear optical properties were determined on a related difunctional dye that can be considered as a representative and simplified model of the trifunctional compounds, determining on it the μβ value of 4950 × 10−48 esu (6111 × 10−80 C2 m4 V−2).The presence of three acrylic or hydroxyl functional groups in the dyes allowed to incorporate the chromophoric fragment into two different kinds of crosslinked materials possessing “frozen” long-lasting dipole order. The traditional guest-host approach used for one of them was exceeded by covalently anchoring the chromophore to a functionalised polymer in a three-dimensional unique network. In this way a promising NLO active material was obtained. The value of the d33 coefficient (determined by SHG measurement using the Maker fringe technique) was 11 pm/V for the poled/crosslinked film. Very good thermal and temporal stability of the chromophore poling-induced dipole alignment was attained.
Journal: Organic Electronics - Volume 10, Issue 1, February 2009, Pages 53–60