کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1268346 972401 2009 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Role of interfacial dipole layer for energy-level alignment at organic/metal interfaces
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Role of interfacial dipole layer for energy-level alignment at organic/metal interfaces
چکیده انگلیسی

The energy-level alignment at Cu-phthalocyanine/metal interfaces has been studied using the Kelvin probe method. The organic layer on a metal surface plays two important roles in the energy-level alignment: the formation of the interfacial dipole (ID) and the passivation of the metal surface. The ID layer determines the injection barrier between the metal and the organic semiconductor. In cases where the lowest unoccupied molecular orbital level of the organic layer on the ID layer is below the Fermi level of the passivated metal substrate, the spontaneous charge transfer from the passivated metal substrate to several organic layers leads to the Fermi-level pinning.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Organic Electronics - Volume 10, Issue 5, August 2009, Pages 990–993
نویسندگان
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