کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1270153 972479 2012 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Ultrasound promoted Wurtz coupling of alkyl bromides and dibromides
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Ultrasound promoted Wurtz coupling of alkyl bromides and dibromides
چکیده انگلیسی

Sonochemically enhanced Wurtz coupling using lithium metal has been investigated for a number of isomeric alkyl bromides under a variety conditions. The products result from direct coupling of short lived radicals formed at the metal surface rather than the secondary radicals which can be formed during coupling of aromatic halides and thus give rise to a single major product. Coupling has been extended to dibrominated aryl and alkyl compounds as well as showing that aryl–alkyl coupling is possible. Dibrominated alkyls were found to give low molecular weight oligomers although no reaction occurred for 1,2-isomers. The growth of oligomers in THF may be solubility limited. A simple model is proposed to explain these findings.


► Wurtz coupling using lithium metal of alkyl bromides.
► Single products formed from short lived radicals, unlike aromatic bromides.
► 1,2-Dibromides do not couple.
► 1,3- and 1,4-Dibromides couple to give oligomers.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ultrasonics Sonochemistry - Volume 19, Issue 1, January 2012, Pages 5–8
نویسندگان
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