کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1301597 | 1498918 | 2016 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
New rhenium(III) semiclathrochelates with biorelevant apical substituents: Synthesis, X-ray structure and reactivity
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: New rhenium(III) semiclathrochelates with biorelevant apical substituents: Synthesis, X-ray structure and reactivity New rhenium(III) semiclathrochelates with biorelevant apical substituents: Synthesis, X-ray structure and reactivity](/preview/png/1301597.png)
چکیده انگلیسی
One-pot reduction-condensation of K2ReCl6, the corresponding α-dioxime and an appropriate boronic acid in the presence of Ag as reductant gave the mixture the boron-capped rhenium(III) tris-dioximates with their reduced diimine-iminoximate derivatives, resulted from the side domino-reaction. Template condensation of nioxime and 3-formylphenylboronic acid on a rhenium(III) ion afforded a formyl-terminated rhenium(III) tris-nioximate, undergoing a further H+-catalyzed condensation with isoniazid as vector substituent to give the semiclathrochelate hydrazone with apical functionalizing group.177
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 72, October 2016, Pages 23-29
Journal: Inorganic Chemistry Communications - Volume 72, October 2016, Pages 23-29
نویسندگان
Alexander S. Belov, Valentin V. Novikov, Genrikh E. Zelinskii, Anna V. Vologzhanina, Oleg A. Varzatskii, Boris F. Myasoedov, Yan Z. Voloshin,