کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1301756 | 1498943 | 2014 | 4 صفحه PDF | دانلود رایگان |
• Four calcium carboxylate frameworks were prepared.
• Cluster- and rod-like building blocks in calcium(II) coordination polymers
• Coordination polymers display lvt-b, pcu, and sql topologies.
Four new calcium carboxylate frameworks, namely Ca2(1,3-bdc)2(nmp)·0.5H2O (1), Ca(1,3-bdc)(pyr) (2), Ca3(1,4-bdc)3(nmp)2 (3), and Ca3(1,4-bdc)3(dmi)4 (4), have been prepared under solvothermal conditions. Compounds 1–3 have 3D framework structures based on rod-like building blocks, while compound 4 has a layered structure constructed from Ca3(CO2)6 clusters. Topological analyses reveal that compounds 2–4 have lvt-b, pcu, and sql topologies, respectively.
Four calcium carboxylate frameworks have been synthesized under solvothermal conditions. These compounds display layered and framework structures constructed from cluster- and rod-like building blocks.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 47, September 2014, Pages 52–55