کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1301810 | 1498952 | 2013 | 5 صفحه PDF | دانلود رایگان |

• The polyoxometalates (POMs) sensitized solar cell (PSSC) was studied firstly.
• It is breakthrough to put forward that POMs export electrons under irradiation.
• The energy level and band gap were investigated for the POMs base sensitizer.
Keggin-type polyoxometalates (POMs) based photosensitizer [(CH3)4N]5[PW11O39RhCH2COOH]∙6H2O (PW11Rh-COOH) was firstly explored for assembling the POMs sensitized solar cells (PSSC). Electrochemical measurement, UV–vis diffuse reflectance spectrum, Surface photovoltage spectrum, and X-ray photoelectron spectroscopy demonstrated that PW11Rh-COOH displayed higher photovoltaic response than that of other POMs because of the better visible-light response, energy level matching and higher carrier separation efficiency.
Keggin-type polyoxometalates (POMs) based photosensitizer [(CH3)4N]5[PW11O39RhCH2COOH]∙6H2O (PW11Rh-COOH) was firstly explored for assembling the POMs sensitized solar cells (PSSC), which displayed higher photovoltaic response than that of other POMs because of the better visible-light response, energy level matching and higher carrier separation efficiency.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 38, December 2013, Pages 78–82