کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1301920 | 1498954 | 2013 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
New hydroxylamine-containing macrobicyclic encapsulating ligand: Unexpected double addition of ethyl radicals to the azomethine fragment of a boron-capped iron(II) clathrochelate dioximate
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: New hydroxylamine-containing macrobicyclic encapsulating ligand: Unexpected double addition of ethyl radicals to the azomethine fragment of a boron-capped iron(II) clathrochelate dioximate New hydroxylamine-containing macrobicyclic encapsulating ligand: Unexpected double addition of ethyl radicals to the azomethine fragment of a boron-capped iron(II) clathrochelate dioximate](/preview/png/1301920.png)
چکیده انگلیسی
The reaction of the mixed dimethylglyoximate-α-benzyldioximate iron(II) clathrochelate with (C2H5)3B-O2 system as “soft” radical source afforded the major macrobicyclic product of reductive addition of two carbon-centered radicals containing both the oxime and hydroxylamine donor groups. This cage complex of new encapsulating ligand was characterized by XRD and solution NMR.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 36, October 2013, Pages 117-121
Journal: Inorganic Chemistry Communications - Volume 36, October 2013, Pages 117-121
نویسندگان
Alexey B. Burdukov, Mikhail A. Vershinin, Evgenii G. Boguslavsky, Ilya V. Eltsov, Galina V. Romanenko, Alexander S. Belov, Yan Z. Voloshin,