A self-assembled non-interpenetrating cubic diamondoid coordination polymer of hexamine with linear dicopper spacer: Structural and magnetic studies

► A new self assembled coordination polymer of CuII, hexamine and benzoate. ► The first cubic non-interpenetrating diamondoid network of μ4-hmt and linear [Cu2(OBz)4] spacer. ► The antiferromagnetic coupling of Cu(II) through the syn-syn carboxylate bridges.