کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1302604 | 974702 | 2007 | 4 صفحه PDF | دانلود رایگان |
The supramolecular structures of two metal complexes, [CuL4Cl2] (1) and [ZnL2Cl2] (2), where L = N-(2,6-dimethylphenyl)-N′-(3-pyridy1)urea, are reported. Complex 1 features infinite tapes formed by intermolecular N–H⋯Cl hydrogen bonds with an R21(6) motif, as well as a π–π stacking interaction. The solid-state structure of 2 shows a 2D network held together by two types of N–H⋯O R21(6) motifs, and there is no significant interaction between the NH groups and the metal-bound Cl− ions.
The syntheses and supramolecular structures of two metal complexes, [CuL4Cl2] (1) and [ZnL2Cl2] (2) (L = N-(2,6-dimethylphenyl)-N′-(3-pyridy1)urea) are reported. Complex 1 features infinite tapes, while 2 shows a 2D network, formed by R21(6) hydrogen bond motifs with either N–H⋯Cl (1) or N–H⋯O (2) contacts.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 10, Issue 5, May 2007, Pages 563–566