کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1302841 974715 2006 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A novel 3D hybrid architecture based on (H2O)6 encircling Cu4I4–O–Cu4I4 cluster and hexanuclear Cu6(datrz)6 ring
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
A novel 3D hybrid architecture based on (H2O)6 encircling Cu4I4–O–Cu4I4 cluster and hexanuclear Cu6(datrz)6 ring
چکیده انگلیسی

The reaction of ligand datrz (3,5-diamino-1,2,4-triazole) with CuI in 1:1 ethanol and water mixed solvent under solvothermal condition gives a novel three-dimensional hybrid solid, [(H3O)2(H2O)4][{Cu6(datrz)6}{(Cu4I4)2O}] (1), which consists of unique six-connected dumb-like Cu4I4–O–Cu4I4 clusters and hexanuclear Cu6(datrz)6 rings. Interestingly, the chair-form water hexamer is firstly observed being interpenetrated by the inorganic cluster.

A novel three-dimensional hybrid solid, [(H3O)2(H2O)4] [{Cu6(datrz)6}{(Cu4I4)2O}] (1), consisting of two kind of unique six-connected SUBs: dumb-like Cu4I4–O–Cu4I4 clusters and hexanuclear Cu6(datrz)6 rings, were synthesized and characterized.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 9, Issue 8, August 2006, Pages 819–822
نویسندگان
, , , , ,