کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1303310 974758 2007 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
[Cu(4,4′-bipy)]2[H4P2W18O62] · 2H2O: The first three-dimensional framework based on saturated Wells–Dawson POMs modified by multi-track Cu–N coordination polymeric chains
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
[Cu(4,4′-bipy)]2[H4P2W18O62] · 2H2O: The first three-dimensional framework based on saturated Wells–Dawson POMs modified by multi-track Cu–N coordination polymeric chains
چکیده انگلیسی

A new double bitrack Cu–N coordination polymeric chain-modified Wells–Dawson POMs, [Cu(4,4′-bipy)]2[H4P2W18O62] · 2H2O (1), has been synthesized and characterized by IR, TG and single crystal X-ray diffraction. It represents the first example that saturated Wells–Dawson POMs are covalently linked by transition metal coordination polymers into a 3D structure. Additionally, its electrochemical property has been studied, undergoing three two-electron reversible redox processes.

A new double bitrack Cu–N coordination polymeric chain-modified Wells–Dawson POMs, [Cu(4,4′-bipy)]2[H4P2W18O62] · 2H2O (1), has been synthesized and characterized, which represents the first example that saturated Wells–Dawson POMs are covalently linked by transition metal coordination polymers into a 3D structure with a (6482)(6482) topology.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 10, Issue 11, November 2007, Pages 1321–1324
نویسندگان
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