کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1303310 | 974758 | 2007 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: [Cu(4,4′-bipy)]2[H4P2W18O62] · 2H2O: The first three-dimensional framework based on saturated Wells–Dawson POMs modified by multi-track Cu–N coordination polymeric chains [Cu(4,4′-bipy)]2[H4P2W18O62] · 2H2O: The first three-dimensional framework based on saturated Wells–Dawson POMs modified by multi-track Cu–N coordination polymeric chains](/preview/png/1303310.png)
A new double bitrack Cu–N coordination polymeric chain-modified Wells–Dawson POMs, [Cu(4,4′-bipy)]2[H4P2W18O62] · 2H2O (1), has been synthesized and characterized by IR, TG and single crystal X-ray diffraction. It represents the first example that saturated Wells–Dawson POMs are covalently linked by transition metal coordination polymers into a 3D structure. Additionally, its electrochemical property has been studied, undergoing three two-electron reversible redox processes.
A new double bitrack Cu–N coordination polymeric chain-modified Wells–Dawson POMs, [Cu(4,4′-bipy)]2[H4P2W18O62] · 2H2O (1), has been synthesized and characterized, which represents the first example that saturated Wells–Dawson POMs are covalently linked by transition metal coordination polymers into a 3D structure with a (6482)(6482) topology.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 10, Issue 11, November 2007, Pages 1321–1324