کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1303646 | 974777 | 2006 | 4 صفحه PDF | دانلود رایگان |
A cadmium metal-organic framework [Cd(μ4-NIPH)(μ2-OH2)]n (1) has been prepared by reaction of H2NIPH (H2NIPH = 5-nitroisophthalic acid) with Cd (II) under hydrothermal condition and characterized by single-crystal X-ray diffraction and TGA analysis. Single crystal X-ray diffraction analysis indicated that 1 is a 2-D layer structure constructed from polynuclear cadmium chains and bridge NIPH ligands. Furthermore, the layers are connected into 3-D supramolecular network through hydrogen bonds. The framework 1 exhibits photoluminescence at room temperature.
The 1 is a novel 2-D cadmium (II) metal-organic framework [Cd(μ4-NIPH)(μ2-OH2)]n constructed from polynuclear cadmium chains and bridge NIPH ligands.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 9, Issue 7, July 2006, Pages 744–747