کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1303801 | 1498958 | 2013 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: NCN palladium pincer via transmercuration. Synthesis of [2-(2-oxazoliny)-6-(2-pyridyl)] phenylpalladium(II) chloride and its catalytic activity in Suzuki coupling NCN palladium pincer via transmercuration. Synthesis of [2-(2-oxazoliny)-6-(2-pyridyl)] phenylpalladium(II) chloride and its catalytic activity in Suzuki coupling](/preview/png/1303801.png)
• An unsymmetrical NCN palladium pincer via organomercurial was synthesized.
• Their UV–vis, single crystal structures were studied.
• This pincer is highly active to Suzuki coupling.
The unsymmetrical NCN ligand 1-(2-oxazolinyl)-3-(2-pyridyl)benzene 6 was synthesized starting from m-bromotoluene after a series of transformations. The reaction of 6 and mercury (II) acetate resulted in mercurial derivative 7 which was transformed into the corresponding NCN palladium pincer 8via transmercuration. The ultraviolet spectra of 6–8 in acetonitrile were also studied. The structures of 6 and 8 were further confirmed by X-ray single crystal diffraction. The carbon–carbon cross coupling reactions between aryl halides and phenylboronic acid catalyzed by 8 were investigated. The results indicate that this palladium pincer is more highly active to the coupling of aryl bromides than aryl chlorides.
NCN ligand 6 is synthesized by a series of transformations starting from 1. Mercuration of 6 and followed by transmetalation affords the palladium pincer 8. This pincer is more highly active to Suzuki coupling.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 32, June 2013, Pages 78–81