کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1303828 | 1498955 | 2013 | 4 صفحه PDF | دانلود رایگان |
• Mixed-valence copper(II)-copper(III) coordination polymer.
• Alternating square planar copper(II) and copper(III) centres.
• Intermolecular Cu-S interactions.
The mixed-valence coordination polymer, [Cu(S2CNPr2)2]2[ClO4], containing both square-planar Cu(II) and Cu(III) centres, has been prepared and crystallographically characterised. In the solid-state it consists of a chain of alternating Cu(II) and Cu(III) centres held together by intermolecular Cu–S interactions, while the perchlorate anions are not metal coordinated. For comparison the crystal structure of [Cu(S2CNPr2)2]2 has been re-determined at 150 K.
The mixed-valence coordination polymer, [Cu(S2CNPr2)2]2[ClO4], has been prepared and crystallographic studies show that it consists of alternating square-planar paramagnetic copper(II) and diamagnetic copper(III) centres, the chain being held together by intermolecular copper–sulphur interactions, while the perchlorate anions are non-coordinating.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 35, September 2013, Pages 65–68