کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1304096 | 1498970 | 2012 | 4 صفحه PDF | دانلود رایگان |
A novel metal-organic framework (MOF), namely, [Ag3(tptz)3(Mo5O17)](H3O)(H2O)1.5 (1), where tptz = 2,4,6-tri(4-pyridyl)-1,3,5-triazine, has been prepared under hydrothermal condition. Compound 1 is a chiral three-fold interpenetrated 3D MOF, in which the [Mo5O17]4 − anions act as templates, encapsulated in the chiral channels of the 3D framework.
A novel 3D POM-templated three-fold interpenetrating MOF based on the rigid 2,4,6-tri(4-pyridyl)-1,3,5-triazine ligand has been successfully synthesized, where the optical band gap and the photoluminescent property have also been investigated.Figure optionsDownload as PowerPoint slideHighlights
► We synthesized an exceedingly rare case of interpenetrating networks with polyoxometalates as templates.
► We investigated the conductivity of the compound.
► We studied the photoluminescent property of the compound.
► The compound is chiral.
► The [Mo5O17]4 − anion in the compound is rare.
Journal: Inorganic Chemistry Communications - Volume 20, June 2012, Pages 131–134