کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1304258 | 1498974 | 2012 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Colorimetric and fluorescence turn-on sensor for biologically important anions based on carbazole derivative Colorimetric and fluorescence turn-on sensor for biologically important anions based on carbazole derivative](/preview/png/1304258.png)
A colorimetric and fluorescent anion chemosensor containing carbazole group has been designed and synthesized based on photoinduced electron transfer (PET). The strong basic anions such as F−, AcO− and H2PO4− resulted in significant red-shift in absorption band and enhancement in fluorescent emission intensity of the compound 1, synchronously accompanied by a “naked eye” color change from light yellow to orange-yellow in organic medium. The determination limit of sensor 1 toward H2PO4− is 1.0 × 10− 6 mol·L− 1. 1H NMR titration experiments shed light on the nature of the interaction between 1 and the anions. Theoretical investigation further illustrated the possible binding mode of host–guest and the roles of molecular frontier orbitals in anion binding.
A colorimetric and fluorescent anion chemosensor based on carbazole derivative has been designed and synthesized based on photoinduced electron transfer (PET). The strong basic anions such as F-, AcO- and H2PO4- resulted in significant red-shift in absorption band and increase in fluorescent emission intensity of the compound, synchronously accompanied by a “naked eye” color change from light yellow to orange-yellow in organic medium. The determination limit of sensor 1 toward H2PO4− is 1.0 × 10− 6 mol·L− 1. Theoretical investigation further illustrated the possible binding mode of host–guest and the roles of molecular frontier orbitals in anion binding.Figure optionsDownload as PowerPoint slideHighlights
► Colorimetric and fluorescence turn-on sensor based on carbazole derivative.
► The interacted mechanism based on photoinduced electron transfer (PET).
► The red-shift in absorption band and increase in emission intensity for H2PO4−.
► The determination limit of the sensor toward H2PO4− is 1.0 × 10− 6 mol·L− 1.
► The roles of molecular frontier orbitals in anion binding.
Journal: Inorganic Chemistry Communications - Volume 16, February 2012, Pages 37–42