کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1304428 | 974825 | 2010 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Rhodium complexes with a new chiral amino-phosphinite ligand and their behavior as pre-catalysts in the hydroformylation of styrene Rhodium complexes with a new chiral amino-phosphinite ligand and their behavior as pre-catalysts in the hydroformylation of styrene](/preview/png/1304428.png)
The new amino-phosphinite chiral ligand (Sa)-4-((S)-1-(diphenylphosphinooxy)-3-methylbutan-2-yl)-4,5-dihydro-3H-dinaphtho[2,1-c:1′,2′-e]azepine (1) has been synthesized and the corresponding more stable oxide has been characterized by X-ray analysis. The ligand behavior in styrene hydroformylation using [Rh(acac)(CO)2] and [Rh(COD)2]BF4 as precursors has been studied. With both pre-catalysts, branched aldehyde 2-phenylpropanal was obtained in mild catalysis conditions with high yield and regioselectivity but as racemic mixture, indicating the loss of the ligand (1) during catalytic run. To support these results, the reactions of [Rh(acac)(CO)2] and [Rh(COD)2]BF4 with the ligand 1 have been performed and the pre-catalysts behavior under CO/H2 has been investigated.
The new amino-phosphinite chiral ligand 1 has been synthesized and the corresponding more stable oxide has been characterized by X-ray analysis. The ligand 1 behavior has been studied in the styrene hydroformylation using [Rh(acac)(CO)2] and [Rh(COD)2]BF4 as precursors. With both pre-catalysts, in mild catalysis conditions, the branched aldehyde 2-phenylpropanal was obtained with high yield and regioselectivity but as a racemic mixture.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 13, Issue 2, February 2010, Pages 215–219