کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1304493 | 974830 | 2010 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Novel chains constructed from heterotrinuclear units and 1,2-bis(4-pyridyl)ethane formulated as [M2M′(O2CPh)6](bpa) (M = Co, Zn, M′ = Co, Cd): Their catalytic activity Novel chains constructed from heterotrinuclear units and 1,2-bis(4-pyridyl)ethane formulated as [M2M′(O2CPh)6](bpa) (M = Co, Zn, M′ = Co, Cd): Their catalytic activity](/preview/png/1304493.png)
Three novel heterometallic complexes containing two bridging ligands bpa and benzoate, formulated as [M2M′(O2CC6H5]n(bpa)n (bpa = 1,2-bis(4-pyridyl)ethane, M2M′ = Zn2Co (1), Zn2Cd (2), and Co2Cd (3)), have been synthesized. All three compounds show one-dimensional structures containing linear heteronuclear coordination units linked by bridging bpa ligands. Reactivity study of the compounds 1–3 for the transesterification of a variety of esters has shown that they are very efficient and 2 is the best among them.
Three novel heterometallic complexes formulated as [M2M’(O2CC6H5]n(bpa)n (M2M′ = Zn2Co (1), Zn2Cd (2), and Co2Cd (3)) have been synthesized. All three compounds show one-dimensional structures containing linear heteronuclear coordination units linked by bridging bpa ligands. Reactivity study of the compounds 1–3 for the transesterification of a variety of esters has shown that they are very efficient and 2 is the best among them.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 13, Issue 1, January 2010, Pages 101–104