کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1304628 | 974840 | 2009 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: A novel polyoxometalate cluster decorated with the directly coordinated organonitrogen ligands: [As(phen)]2[As2Mo2O14] A novel polyoxometalate cluster decorated with the directly coordinated organonitrogen ligands: [As(phen)]2[As2Mo2O14]](/preview/png/1304628.png)
A novel organic–inorganic molybdenum arsenate compound with chain structure, [As(phen)]2[As2Mo2O14] (phen = 1,10′-phenanthroline) 1, has been synthesized by the hydrothermal reaction and structurally characterized. Compound 1 represents the first example which contains an unusual 1D {As/Mo/O} chain with the phen ligands directly coordinated to the As atoms. Furthermore, a two-dimensional supramolecule layer is formed by π–π stacking interactions of the phen groups between adjacent chains. The electrochemical behavior of 1 modified CPE (1-CPE) has been also studied.
A novel 1D chained organic–inorganic molybdenum arsenate compound decorated with the directly coordinated organonitrogen ligands: [As(phen)]2[As2Mo2O14] is reported for the first time. Furthermore, a two-dimensional supermolecule layer structure is formed by π–π stacking interactions of the phen groups between adjacent chains.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 12, Issue 2, February 2009, Pages 65–68