کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1304938 1498976 2007 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
An unprecedented 2D isopolymolybdate with (32·4)(32·53·8)(3·42·54·6·82)(34·43·54·64) topology
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
An unprecedented 2D isopolymolybdate with (32·4)(32·53·8)(3·42·54·6·82)(34·43·54·64) topology
چکیده انگلیسی

A novel two-dimensional molybdenum oxide polymer, [Mo4O13]n · 2nH3O, has been prepared under specific hydrothermal conditions and characterized by IR spectroscopy and TG analysis. Single-crystal X-ray diffraction analysis reveals that compound 1 exhibits a (3, 4, 5, 6)-connected 2D layer structure with (32·4)(32·53·8)(3·42·54·6·82)(34·43·54·64) topology, which is constructed by two parallel molybdenum oxide dimeric chains (Mo2O10)n bound together by the dimer of Mo2O9 subunits via the sharing of corners. Additionally, the electrochemistry activity of compound 1 is also reported.

[Mo4O13]n · 2nH3O: the first (3, 4, 5, 6)-connected two-dimensional framework constructed from isopolymolybdate with (32·4)(32·53·8)(3·42·54·6·82)(34·43·54·64) topology.A novel two-dimensional molybdenum oxide polymer, [Mo4O13]n · 2nH3O, has been synthesized and represents the first example of 2D layer structure with (32·4)(32·53·8) (3·42·54·6·82)(34·43·54·64) topology, in which two parallel molybdenum oxide dimeric chains (Mo2O10)n are bound together by the dimer of Mo2O9 subunits via the sharing of corners.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 10, Issue 12, December 2007, Pages 1469–1472
نویسندگان
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