کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1304976 | 974864 | 2007 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Anion effect on construction of zinc(II) coordination polymer with a chelating ligand 2,2′-dipyridylamine (Hdpa): Novel heterogeneous catalytic activities Anion effect on construction of zinc(II) coordination polymer with a chelating ligand 2,2′-dipyridylamine (Hdpa): Novel heterogeneous catalytic activities](/preview/png/1304976.png)
The reaction of ZnSO4 with 2,2′-dipyridylamine (Hdpa) results in a coordination polymer 1 while other zinc(II) salts (bromide 2 or benzoateanions 3) produce usually monomers which can generate hydrogen-bonded polymers. The coordination polymer 1 and hydrogen-bonded polymer 2 have shown, surprisingly, unusual heterogeneous catalytic activities on transesterification reaction of esters, but the monomeric compound 3 catalyzed the reaction homogeneously.
The reaction of ZnSO4 with 2,2′-dipyridylamine (Hdpa) results in a coordination polymer 1 while other zinc(II) salts (bromide 2 or benzoateanions 3) produce usually monomers which can generate hydrogen-bonded polymers. The coordination polymer 1 and hydrogen-bonded polymer 2 have shown, surprisingly, unusual heterogeneous catalytic activities on transesterification reaction of esters, but the monomeric compound 3 catalyzed the reaction homogeneously..Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 10, Issue 3, March 2007, Pages 287–291