کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1305204 | 1498920 | 2016 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A metal-organic polyhedron based on dibenzothiophene ligand: Gas adsorption and reductive properties
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
• A new metal organic polyhedron Cu-MOP based on a dibenzothiophene ligand has been synthesized and characterized.
• Cu-MOP showed H2 and CO2 sorption behavior over N2.
• TCNQ, DDQ, CR and MB could be reduced in the presence of Cu-MOP.
A new metal–organic polyhedron Cu-MOP with octahedral geometry was constructed by 2,8-dibenzothiophenedicarboxylic acid and dicopper paddlewheel. Cu-MOP exhibited H2 and CO2 sorption behavior. Furthermore, Cu-MOP revealed reductive properties towards TCNQ, DDQ, CR and MB due to the electron-donating nature of DBT ligand.
A new metal organic polyhedron Cu-MOP based on a dibenzothiophene ligand showing gas sorption and reductive properties.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 70, August 2016, Pages 10–13
Journal: Inorganic Chemistry Communications - Volume 70, August 2016, Pages 10–13
نویسندگان
Sha Ma, Yanfei Niu, Xiaoli Zhao, Zhiming Duan,