کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1305217 1498920 2016 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Bis(di-2-pyridyl ketoximate-O,N,N′)bis(di-2-pyridyl ketoxime-N,N′)dicopper(II) diperchlorate: A plausible, weakly ferromagnetically-coupled intermediate in the formation of the neutral, strongly antiferromagnetically-coupled neutral dimer bearing only dep
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Bis(di-2-pyridyl ketoximate-O,N,N′)bis(di-2-pyridyl ketoxime-N,N′)dicopper(II) diperchlorate: A plausible, weakly ferromagnetically-coupled intermediate in the formation of the neutral, strongly antiferromagnetically-coupled neutral dimer bearing only dep
چکیده انگلیسی


• A cationic dinuclear copper(II) complex with a double oximato bridge has been prepared.
• The complex is a synthetic intermediate of the corresponding neutral dimer.
• The complex is characterized by a weak ferromagnetic exchange interaction.

Complex [Cu2{(py)2CNO}2{(py)2CNOH}2](ClO4)2 (2) has been isolated and proven to be an intermediate of the reaction that leads to the known, neutral dimer [Cu2{(py)2CNO}4]·2H2O (1), where (py)2CNOH = di-2-pyridyl ketoxime; the different topologies of the double oximato bridge in the two complexes lead to different magnetic responses.

Bis(di-2-pyridyl ketoximate)bis(di-2-pyridyl ketoxime)dicopper(II) diperchlorate contains a double diatomic oximato bridge which promotes an unusual ferromagnetic exchange interaction between the spin carriers; it is a synthetic intermediate in the formation of the corresponding neutral dimer that possesses exclusively deprotonated organic ligands.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 70, August 2016, Pages 95–98
نویسندگان
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