کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1305630 | 1498964 | 2012 | 4 صفحه PDF | دانلود رایگان |
A novel coordination polymer [Co(bpbc)(H2O)2]n (1) was synthesized by hydrothermal reaction of Co(OAc)2·2H2O and 2,2′-bipyridine-4,4′-dicarboxylate acid (H2bpbc). X-ray single diffraction studies reveal that compound 1 exhibits chiral two-fold interpenetrating 3-D network, which contains different numbers of left- and right-handed helical chains. The magnetic property is also investigated.
An unusual chiral interpenetrating coordination polymer is synthesized by rigid organic ligand, which contains different numbers of left- and right-handed helical chains.Figure optionsDownload as PowerPoint slideHighlights
► Rigid bifunctional ligand was used to construct chiral interpenetration coordination polymer.
► This chiral coordination polymer is constructed by different numbers of left- and right‐handed helical chains.
► Antiferromagnetic coupling dominating the magnetic properties.
Journal: Inorganic Chemistry Communications - Volume 26, December 2012, Pages 7–10