کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1305864 975053 2011 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A unique, rigid porous coordination polymer with 1,4,5-triazanaphthalene and mixed-valence Cu as the bridging metal
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
A unique, rigid porous coordination polymer with 1,4,5-triazanaphthalene and mixed-valence Cu as the bridging metal
چکیده انگلیسی

A novel mixed-valence Cu(I)/Cu(II) compound with the bridging ligand 1,4,5-triazanaphthalene (tan) is reported, having the overall formula [Cu2(tan)4](ClO4)3. The synthesis, X-ray crystal structure and preliminary spectroscopic properties are presented. The coordination of Cu(I) is tetrahedral, and that of Cu(II) is square planar. The packing of the units generates a 3D network with spaces in the cavities, available for the counter anions and accessible for small solvent molecules.

Graphical AbstractA novel mixed-valence porous Cu compound consisting of 1,4,5-triazanaphthalene bridging ligands is described.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 14, Issue 1, January 2011, Pages 162–165
نویسندگان
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