کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1306121 | 975067 | 2009 | 4 صفحه PDF | دانلود رایگان |
Two novel copper(II) complexes, namely [Cu(phen)(L)2]·6H2O (1) and [Cu(phen)3]·(ClO4)2 (2) have been synthesized under mild condition (HL = 5-methyl-1H-pyrazole-3-carboxylic acid, phen = 1,10-phenanthroline). We report the structural evidence of discrete water decamer conformation in the solid state. These units are found to act as supramolecular glue in the aggregation of mononuclear copper(II) complex to give a three-dimensional network through hydrogen-bonding. The preliminary investigation on the thermal behavior and the anion exchange property of the complexes are presented.
A novel Cu(II) complex with pyrazole and 1,10-phenanthroline ligands, which contain supramolecular (H2O)10 morphology. The hydrogen-bonding association leads to the formation of the infinite morphology of water molecules along the b-axis.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 12, Issue 12, December 2009, Pages 1189–1192