کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1306226 | 975076 | 2009 | 5 صفحه PDF | دانلود رایگان |
Novel magnesium and metal-free porphyrazines (4 and 5) containing four peripheral tetrathiacrown ether-linked tetrathiafulvalene moieties have been synthesized and characterized. Their solution electrochemical data showed two reductive and three oxidative processes within a −1500 mV to +1500 mV potential window. UV/Vis spectroscopy and electron paramagnetic resonance (EPR) measurements reveal the formation of a charge-transfer complex between porphyrazine 4 with F4TCNQ. The single-crystal structure of the TTF-dicyanocrown ether 3 is presented.
Novel magnesium and metal-free porphyrazines (4 and 5) containing four peripheral tetrathiacrown ether-linked tetrathiafulvalene moieties have been synthesized and studied their electron donating properties.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 12, Issue 8, August 2009, Pages 739–743