Solvothermal synthesis and crystal structure of a luminescent 2D copper(I) coordination polymer with a (3,4)-connected net

A novel 2D coordination polymer {[Cu(tpt)(MeCN)](ClO4)}∞ (1) (tpt = 2,4,6-tris(4-pyridyl)-1,3,5-triazine), was prepared by reactions of [Cu(MeCN)4](ClO4) and excess tpt under the solvothermal conditions. The molecular structure of 1 was characterized by elemental analysis, IR, and X-ray crystallography and its luminescent properties were studied.