کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1313732 | 1499321 | 2015 | 10 صفحه PDF | دانلود رایگان |
• 1,1-Difluoro-1-alkenes bearing a biphenyl skeleton were treated with a cationic palladium(II) catalyst.
• The Friedel–Crafts-type cyclizations of difluoroalkenes afforded pinpoint-fluorinated phenanthrenes via CF bond activation.
• The packing structure of the products was investigated by single-crystal X-ray structure analysis.
• Columnar and layer structures in the solid state were observed.
Treatment with a cationic palladium(II) catalyst promoted the Friedel–Crafts-type cyclization of 1,1-difluoro-1-alkenes bearing a biphenyl skeleton to afford regioselectively fluorinated (pinpoint-fluorinated) phenanthrenes via CF bond activation. The obtained pinpoint-fluorinated phenanthrenes were observed to be organized by π–π and CH⋯F interactions to exhibit columnar and layer structures in the solid state.
Treatment with a cationic palladium(II) catalyst promoted the Friedel–Crafts-type cyclization of 1,1-difluoro-1-alkenes bearing a biphenyl skeleton to afford regioselectively fluorinated (pinpoint-fluorinated) phenanthrenes via CF bond activation. The obtained pinpoint-fluorinated phenanthrenes were observed to be organized by π–π and CH⋯F interactions to exhibit columnar and layer structures in the solid state.Figure optionsDownload as PowerPoint slide
Journal: Journal of Fluorine Chemistry - Volume 179, November 2015, Pages 106–115