کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1313820 1499332 2014 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
1:1 and 2:1 cocrystallizations of alkoxy-substituted naphthalene derivatives with octafluoronaphthalene through arene–perfluoroarene interactions
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
1:1 and 2:1 cocrystallizations of alkoxy-substituted naphthalene derivatives with octafluoronaphthalene through arene–perfluoroarene interactions
چکیده انگلیسی


• Alkoxy substituted naphthalenes were cocrystallized with octafluoronaphthalene.
• Arene–perfluoroarene interaction is observed in the cocrystals.
• The 2:1 cocrystal is rare example and each π-plane was highly overlapped.
• Alkoxy groups at 2,7-position in naphthalene are effective for the cocrystallization.
• Propoxy group is optimal to have possible CH⋯F interactions to give cocrystals.

Naphthalene derivatives with laterally orientated short side chains readily form cocrystals with octafluoronaphthalene in which the position and the length of the lateral chain can control the 1:1 and 2:1 cocrystallization stoichiometries and overlapped areas of the π-planes, showing that the systematic substitution patterns in the chains of molecules can be exploited to rationally designed cocrystals.

Naphthalene derivatives with laterally orientated short side chains readily form unique 1:1 and 1:2 cocrystals with octafluoronaphthalene through arene–perfluoroarene interactions.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Fluorine Chemistry - Volume 168, December 2014, Pages 193–197
نویسندگان
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