کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1315245 | 976014 | 2009 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Unexpected high regiocontrol in Heck reaction of fluorine-containing electron-deficient olefins—Highly regio- and stereoselective synthesis of β-fluoroalkyl-α-aryl-α,β-unsaturated ketones
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Unexpected high regiocontrol in Heck reaction of fluorine-containing electron-deficient olefins—Highly regio- and stereoselective synthesis of β-fluoroalkyl-α-aryl-α,β-unsaturated ketones Unexpected high regiocontrol in Heck reaction of fluorine-containing electron-deficient olefins—Highly regio- and stereoselective synthesis of β-fluoroalkyl-α-aryl-α,β-unsaturated ketones](/preview/png/1315245.png)
چکیده انگلیسی
Treatment of (E)-4,4,4-trifluoro-1-aryl-2-buten-1-one with various aryldiazonium salts in the presence of palladium catalyst gave the corresponding α-arylated Heck adducts with high regio- and stereoselectivity in good to high yields.
Treatment of (E)-4,4,4-trifluoro-1-aryl-2-buten-1-one with various aryldiazonium salts in the presence of palladium catalyst gave the corresponding α-arylated Heck adducts with high regio- and stereoselectivity in good to high yields.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Fluorine Chemistry - Volume 130, Issue 10, October 2009, Pages 913–921
Journal: Journal of Fluorine Chemistry - Volume 130, Issue 10, October 2009, Pages 913–921
نویسندگان
Tsutomu Konno, Shigeyuki Yamada, Akinori Tani, Masataka Nishida, Tomotsugu Miyabe, Takashi Ishihara,