کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1315698 | 976059 | 2006 | 4 صفحه PDF | دانلود رایگان |
Ring-opening fluorination reactions of epoxides using tetrabutylammonium bifluoride (TBABF)-KHF2, or Et3N-3HF under microwave irradiation were applied for the introduction of a fluorine atom into the carbohydrate molecules. When TBABF-KHF2 was used as the fluorination reagent, a fluorine atom was introduced regioselectively and various functional groups can tolerate the conditions. When Et3N-3HF was used under microwave irradiation, the reaction time could be remarkably shortened compared with the conventional oil-bath heating.
Ring-opening fluorination reactions of epoxides using tetrabutylammonium bifluoride (TBABF)-KHF2, or Et3N-3HF under microwave irradiation were applied for the introduction of a fluorine atom into the carbohydrate molecules. Figure optionsDownload as PowerPoint slide
Journal: Journal of Fluorine Chemistry - Volume 127, Issue 7, July 2006, Pages 920–923