کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1315740 | 976064 | 2006 | 5 صفحه PDF | دانلود رایگان |
New highly fluorinated derivatives of phenazine which are difficult to obtain in other ways, namely 1,2,2,3,4-pentafluoro-10-(2,3,4,5,6-pentafluorophenyl)-2,10-dihydrophenazine (2) and its hydrolyzed product 1,3,4-trifluoro-10-(2,3,4,5,6-pentafluorophenyl)-2(10H)-phenazinone (3), were both synthesized and characterized by means of single-crystal X-ray analysis and 1H, 19F NMR spectroscopy. Correlation between the results of X-ray analysis and NMR spectroscopy is established. The formation mechanism of 2 involving oxidation of a cobalt complex bearing two noninnocent o-benzosemiquinonediiminato(1-) ligands is proposed.
Synthesis of two new phenazine derivatives and their X-ray structures are reported. Figure optionsDownload as PowerPoint slide
Journal: Journal of Fluorine Chemistry - Volume 127, Issue 2, February 2006, Pages 200–204