کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1334657 1500289 2013 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and magnetic characterization of a cubane-type Mn4 cluster, housed in a sterically hindered carboxylate ligand pocket
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis and magnetic characterization of a cubane-type Mn4 cluster, housed in a sterically hindered carboxylate ligand pocket
چکیده انگلیسی

The use of sterically hindered terphenyl-based carboxylate, −O2CAr4F-Ph, in manganese (II) chemistry has yielded a new cubane-type Mn4 cluster, in which four Mn(II) sites have slightly distorted octahedral geometries with a distinctive O6 donor atom sets. Based on the total energy calculations for magnetic states of the cluster using the LDA + U method, two kinds of magnetic exchange coupling interactions between Mn(II) sites are chosen to fit the measured magnetic properties, resulting in weak intra-molecular antiferromagnetic interactions (J = −1.91 K, J′ = −3.07 K, and g = 2.00).

The new cubane-type Mn4 complex with the distinct oxygen rich coordination environment displays two kinds of intra-molecular antiferromagnetic exchange coupling interactions between Mn(II) sites (J = −1.91 K, J′ = −3.07 K, and g = 2.00).Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 50, Issue 1, 13 February 2013, Pages 339–344
نویسندگان
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