کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1334687 1500289 2013 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Calix[4]arene based fluorescent chemosensor bearing coumarin as fluorogenic unit: Synthesis, characterization, ion-binding property and molecular modeling
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Calix[4]arene based fluorescent chemosensor bearing coumarin as fluorogenic unit: Synthesis, characterization, ion-binding property and molecular modeling
چکیده انگلیسی

A series of calix[4]arene-based fluorescent chemosensors in cone and 1,3-alternate conformations have been synthesised incorporating ethylene glycol units as binding sites and coumarin as fluorescent probe. These compounds have been designed with variation in substituents, conformations of the calixarene unit and steric crowding. The open chain ethylene glycol moieties are flexible so that they can orient themselves in space to make effective interactions with metal ions. Ion-binding study of these fluoroionophores has been carried out using a large number of metal ions and the ion recognition event is monitored by fluorescence and absorption spectroscopy. Substantial quenching in emission intensity in presence of Fe3+ and Cu2+ and enhancement of emission intensity in presence of Ca2+ suggests strong binding of these metal ions with the ionophores. Complexation with these metal ions is also evident from UV–Vis spectral changes. Composition of the complexes formed (1:1) has been confirmed by ESMS analysis. Binding constants with the strongly interacting metal ions have been evaluated from fluorescence titration data. DFT calculations have been carried out to find out the metal binding sites of the calix ionophores and frontier molecular orbital analyses have rationalized the fluorescence behaviors observed upon complexation with metal ions in these cases.

Ion-binding study of calix[4]arene based fluoroionophores containing ethylene glycol moieties as coordinating sites and coumarin as fluorogenic probe exhibit strong complexation with Fe3+ and some cases also with Cu2+ and Ca2+. DFT calculations revealed sites for metal interaction and frontier molecular orbital analyses rationalized the fluorescence behavior of ionophores upon binding with metal ions.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 50, Issue 1, 13 February 2013, Pages 592–601
نویسندگان
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