کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1334729 | 979446 | 2012 | 13 صفحه PDF | دانلود رایگان |
Copper(II) complexes of amidinoisourea and biguanidine derivatives [Cu{NH2(CNH)NH(CNH)Y}Y]2 (NO3)2, where Y = OR, NHR or NRR (R = Me, Et, Pr, iPr, allyl, Bu, iBu, Bz, Cp, Cy) suitable for inflating gas generating systems were synthesized and characterized by elemental analysis, mass spectrometry and FTIR spectroscopy. The structures of three complexes were determined by X-ray diffraction. Thermal behavior was studied by differential thermal analysis and the decomposition temperatures indicated good thermal stability. Enthalpies of formation of the complexes are influenced by the substituent Y.
Copper(II) complexes of amidinoisourea and biguanidine derivatives [Cu{NH2(CNH)NH(CNH)Y}Y]2 (NO3)2, where Y = OR, NHR or NRR (R = Me, Et, Pr, iPr, allyl, Bu, iBu, Bz, Cp, Cy) suitable for inflating gas generating systems were synthesized and characterized by elemental analysis, mass spectrometry and FTIR spectroscopy. The structures of three complexes were determined by X-ray diffraction. Thermal behavior was studied by differential thermal analysis and the decomposition temperatures indicated good thermal stability. Enthalpies of formation of the complexes are influenced by the substituent Y.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 44, Issue 1, 31 August 2012, Pages 88–100