کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1335362 | 979526 | 2007 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis, structure and theoretical study of two rhodium(I) complexes [Rh(TropNMe)(CO)(PPh3)] and [Rh(Trop)(CO)(PPh3)] · Acetone Synthesis, structure and theoretical study of two rhodium(I) complexes [Rh(TropNMe)(CO)(PPh3)] and [Rh(Trop)(CO)(PPh3)] · Acetone](/preview/png/1335362.png)
Rhodium(I) complexes [Rh(TropNMe)(CO)(PPh3)] (TropNMe = 2-(N-methylamino)tropone, ONC8H9) (1) and [Rh(Trop)(CO)(PPh3)] · Acetone (Trop = Tropolone, O2C7H6) (2) have been synthesized and characterized by single-crystal X-ray diffraction analysis. A distorted square planar geometry about the rhodium(I) metal centre is observed in both compounds 1 and 2. Substitution of an oxygen atom with a methyl functionalized nitrogen atom does not significantly alter the bond distances and angles in the rhodium(I) complex. A theoretical study at B3LYP/6-31G(d) (main group) and LANL2DZ (Rh) level is presented to clarify the solid state behaviour of these complexes.
Rhodium(I) complexes [Rh(TropNMe)(CO)(PPh3)] (1) and [Rh(Trop)(CO)(PPh3)] · Acetone (2) have been synthesized and characterized by single-crystal X-ray diffraction analysis. Substitution of an oxygen atom with a methyl functionalized nitrogen atom does not significantly alter the bond distances and angles in the rhodium(I) complex. A theoretical study is presented to clarify the solid state behaviour of these complexes.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 26, Issue 18, 20 November 2007, Pages 5324–5330