کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1335645 | 979541 | 2006 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Mechanistic study of quinoliniumdichromate (QDC) oxidation of mercury(I) in aqueous sulfuric acid in the presence of micro amounts of palladium(II) - Autocatalysis in catalysis
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Mechanistic study of quinoliniumdichromate (QDC) oxidation of mercury(I) in aqueous sulfuric acid in the presence of micro amounts of palladium(II) - Autocatalysis in catalysis Mechanistic study of quinoliniumdichromate (QDC) oxidation of mercury(I) in aqueous sulfuric acid in the presence of micro amounts of palladium(II) - Autocatalysis in catalysis](/preview/png/1335645.png)
چکیده انگلیسی
The kinetics of oxidation of mercury(I) with quinoliniumdichromate (QDC) in the presence of micro amounts of palladium(II) catalyst in aqueous sulfuric acid medium has been studied. The active species of oxidant, reductant and catalyst in the reaction medium were understood to be HCrO4-, [Hg2(SO4)HSO4]â and PdCl+, respectively. The autocatalysis by one of the products, chromium(III), was observed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 25, Issue 15, 3 November 2006, Pages 2976-2984
Journal: Polyhedron - Volume 25, Issue 15, 3 November 2006, Pages 2976-2984
نویسندگان
S.A. Chimatadar, T. Basavaraj, S.T. Nandibewoor,