کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1335650 979541 2006 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis of a bis(oxazoline)-N-carboxylate ligand and its Zn(II) complex that shows C–H⋯Cl hydrogen bonding
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis of a bis(oxazoline)-N-carboxylate ligand and its Zn(II) complex that shows C–H⋯Cl hydrogen bonding
چکیده انگلیسی

An efficient synthesis of a novel N3O-type chelate and its Zn(II) complex is described. The Zn(II) complex shows C–H⋯Cl–Zn hydrogen bonding both in the solid and solution states. The chelate, (S,S)-[bis{(4-isopropyl-4,5-dihydrooxazol-2-yl)methyl}amino]acetic acid sodium salt, is a new and branched type of N3O ligand, featuring C2-symmetric bis(oxazoline)-N-carboxylate. A key step of the ligand synthesis involved a stepwise introduction of the oxazoline rings to suppress side products otherwise resulted from one-step approach. Treatment of the sodium bis(oxazoline)-N-carboxylate with ZnCl2 and subsequent removal of NaCl resulted in the corresponding Zn(II) complex. The Zn(II) complex showed an unusual downfield shift by the isopropyl methine protons on its 1H NMR spectrum, which suggests the C–H⋯Cl–Zn hydrogen bonding. An X-ray crystallographic analysis of the single crystals of the Zn(II) complex supports the C–H⋯Cl–Zn hydrogen bonding, showing a microchannel structure that encapsulates a linear array of chloroform molecules through other intermolecular hydrogen bonding interactions.

A novel N3O-type chelate and its Zn(II) complex are synthesized. The chelate is a branched type N3O ligand, (S,S)-[Bis{(4-isopropyl-4,5-dihydrooxazol-2-yl)methyl}amino]acetic acid sodium salt, which was synthesized through a stepwise introduction of the oxazoline rings. The Zn(II) complex shows C–H⋯Cl–Zn hydrogen bonding both in the solid and solution states. A single crystal X-ray analysis of the Zn(II) complex supports the C–H⋯Cl–Zn hydrogen bonding, showing a microchannel structure.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 25, Issue 15, 3 November 2006, Pages 3025–3031
نویسندگان
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